Recent

  1. Vatankhah-Varnosfaderani, M.; Keith, A.N.; Cong, Y.; Liang, H.; Rosenthal, M.; Sztucki, M.; Clair, C.; Magonov, S.; Ivanov, D.A.; Dobrynin, A.V.; Sheiki, S.S. "Chameleon-like Elastomers with Molecularly Encoded Strain-adaptive Stiffening and Coloration" Science, 359, 1509-1513 (2018) DOI: 10.1126/science.aar5308.
  2. Wan, X.; Min, Y.; Bludau, H.; Keith, A.; Sheiko, S.S.; Jordan, R.; Wang, A.Z.; Sokolsky-Papkov, M.; Kabanov, A.V. "Drug Combination Synergy in Worm-like Polymeric Micelles Improves Treatment Outcome for Small Cell and Non-Small LUng Cancer" ACS Nano., 12, 2426-2439 (2018) DOI: 10.1021/acsnano.7b07878.
  3. Liang, H.; Sheiko, S.S.; Dobrynin, A.V. "Supersoft and Hyperelastic Polymer Networks with Brushlike Strands" Macromolecules, 51, 638-645 (2018) DOI: 10.1021/acs.macromol.7b02555
  4. Vatankhah-Varnosfaderani, M.; Daniel, W.F.M.; Everhart, M.H.; Pandya, A.A.; Liang, H.; Matyjaszewski, K.; Dobrynin, A.V.; Sheiko, S.S. "Mimicking Biological Stress–strain Behaviour with Synthetic Elastomers" Nature 549, 497-501 (2017) DOI: 10.1038/nature23673
  5. Ina, M.; Cao, Z.; Vatankhah-Varnosfaderani, M.; Everhart, M.H.; Daniel, W.F.M.; Dobrynin, A.V.; Sheiko, S.S. "From Adhesion to Wetting: Contact Mechanics at the Surfaces of Super-Soft Brush-Like Elastomers" ACS Macro Lett. 6, 854-858 (2017) DOI: 10.1021/acsmacrolett.7b00419
  6. Guan, Q.; Picken, S.J.; Sheiko, S.S.; Dingemans, T.J. "High-Temperature Shape Memory Behavior of Novel All-Aromatic (AB)n-Multiblock Copoly(ester imide)s" Macromolecules 50, 3903-3910 (2017) DOI: 10.1021/acs.macromol.7b00569
  7. Liang, H.; Cao, Z.; Wang, Z.; Sheiko, S.S.; Dobrynin, A.V. "Combs and Bottlebrushes in a Melt" Macromolecules 50, 3430-3437 (2017) DOI: 10.1021/acs.macromol.7b00364
  8. Daniel, W.F.M.; Xie, G.; Vatankhah-Varnosfaderani, M.; Burdynska, J.; Li, Q.; Nykypanchuk, D.; Gang, O.; Matyjaszewski, K.; Sheiko, S.S. "Bottlebrush-Guided Polymer Crystallization Resulting in Supersoft and Reversibly Moldable Physical Networks" Macromolecules 50, 2103-2111 (2017) DOI: 10.1021/acs.macromol.7b00030
  9. Piszkiewicz, S.; Mehta, A.; Boothby, T.C.; Daniel, W.; Sheiko, S.S.; Goldstein, B.; Pielak, G.J. "Tardigrade Intrinsically Disordered Proteins as Potential Excipients for Biologics" Biophysical Journal (2017) DOI: 10.1016/j.bpj.2016.11.2766
  10. Hu, X.; Zhou, J.;Daniel, W.F.M.; Vatankhah-Varnosfaderani, M.; Li, Q., Zhushma, A.P.; Dobrynin, A.V.; Sheiko, S.S. "Dynamics of Dual Networks: Strain Rate and Temperature Effects in Hydrogels with Reversible H-bonds” Macromolecules 50, 652-659 (2017) DOI: 10.1021/acs.macromol.6b02422
  11. Paturej, J.; Sheiko, S.S.; Panyukov, S.; Rubinstein, M. “Molecular structure of bottlebrush polymers in melts” Science Advances, in press (2016). DOI: 10.1126/sciadv.1601478
  12. Vatankhah-Varnosfaderani, M.; Daniel, W.F.M.; Zhushma, A.P.; Li, Q., Morgan, B.J.; Matyjaszewski, K.; Armstrong, D.P.; Spontak, R.J.; Dobrynin, A.V.; Sheiko, S.S. “Bottlebrush elastomers: A new platform for freestanding electroactuation” Adv. Mater. 29, 1604209 (2016) DOI: 10.1002/adma.201604209
  13. Vatankhah-Varnosfaderani, M.V.; Ina, M.; Adelnia, H.; Li, Q.; Zhushma, A.; Hall, L.J..; Sheiko, S.S. “Well-Defined Zwitterionic Microgels: Synthesis and Application as Acid-Resistant Microreactors” Macromolecules 49, 7204-7210 (2016). DOI: 10.1021/acs.macromol.6b01713
  14. Olson, K.R.; Wong, D.H.C.; Chintapalli, M.; Timachova, K.; Janusziewicz, R.; Daniel, W.F.M.; Mecham, S.; Sheiko, S.S.; Balsara, N.; DeSimone, J.M. “Liquid Perfluoropolyether Electrolytes with Enhanced Ionic Conductivity for Lithium Battery Applications" Polymer 100, 126-133 (2016).
  15. Cao, Z,; Daniel, W.F.M.; Vatankhah-Varnosfaderani, M.; Sheiko, S.S.; Dobrynin, A.V.D. “Dynamics on bottlebrush networks. ” Macromolecules 49, 8009-8017 (2016). DOI: 10.1021/acs.macromol.6b01358
  16. Hu, X.; Zhou, J.; Vatankhah-Varnosfaderani, M.; Daniel, W.F.M.; Li, Q., Zhushma, A.P.; Dobrynin, A.V.; Sheiko, S.S. “Programming Temporal Shapeshifting” Nature Comm. 7, 12919 (2016). DOI: 10.1038/ncomms12919
  17. Ina, M.; Zhushma, A.P.; Lebedeva, N.V.; Vatankhah-Varnosfaderani, M; Olson, S.D.; Sheiko, S.S. “The design of wrinkled microcapsules for enhancement of release rate” J. Coll. Interf. Sci. 478, 296-302 (2016). DOI: 10.1016/j.jcis.2016.06.022
  18. Xie, G.; Ding, H.; Daniel, W. F. M.; Wang, Z.; Pietrasik, J.; Sheiko, S. S.; Matyjaszewski, K., "Preparation of titania nanoparticles with tunable anisotropy and branched structures from core–shell molecular bottlebrushes". Polymer 98, 481-486 (2016). DOI:10.1016/j.polymer.2016.03.032
  19. Lebedeva, N.V.; Sanders, S.N.; Ina, M.; Zhushma, A.; Olson, S.D.; Rubinstein, M.; Sheiko, S.S. “Multicore expandable microbubbles: Controlling density and expansion temperature.” Polymer 90, 45-52 (2016). DOI: 10.1016/j.polymer.2016.02.050
  20. Vatankhah-Varnosfaderani, M.V.; Zhushma, A.; Everhart, M.H.; Ina, M.; Rubinstein, M.; Sheiko, S.S. “Submicrometer-Encapsulation of NaBH4 by Dopamine End-Functionalized Polystyrene: Gas Generation at Oil-Water Interfaces” Chem. Mater. 28, 2928-2933 (2016). DOI: 10.1021/acs.chemmater.5b04624
  21. Li, Q.; Zhou, J.; Vatankhah-Varnosfaderani, M.; Nykypanchuk, D.; Gang, O.; Sheiko, S.S. “Advancing Reversible Shape Memory by Tuning the Polymer Network Architecture" Macromolecules 49, 1383-1391 (2016). DOI: 10.1021/acs.macromol.5b02740
  22. Li, Y.; Niu, Z.; Burdynska, J.; Nese, A.; Zhou, Y.; Kean, Z.S.; Dobrynin, A.V.; Matyjaszewski, K.; Craig, S.L. Sheiko, S.S. “Sonication-Induced Scission of Molecular Bottlebrushes: Implications of the “Hairy” Architecture” Polymer 84, 178-184 (2016) DOI: 10.1016/j.polymer.2015.12.044
  23. Daniel, W.F.M.; Burdyńska,J.; Vatankhah-Varnoosfaderani, M.V.; Matyjaszewski, K.; Paturej, J.; Rubinstein, M.; Dobrynin, A.D.; Sheiko, S.S. “Solvent-free, supersoft and superelastic bottlebrush melts and networks.” Nature Materials 15, 183-189 (2016). DOI: 10.1038/nmat4508

2015 - 2010

  1. Hu, X.; Vatankhah-Varnoosfaderani, M.; Zhou, J.; Li, Q., and Sheiko, S.S. “Weak Hydrogen Bonding Enables Hard, Strong, Tough, and Elastic Hydrogels” Advanced Mater. 27, 6899-6905 (2015) DOI: 10.1002/adma.201503724.
  2. Borner, H.G. ; Hoger, S.; Rosselli, S.; Sheiko, S.S. “Synthesis of conjugates combining macromolecular brushes and rigid macrocycles.” Polymer 72, 422-427 (2015) DOI: 10.1016/j.polymer.2015.02.059
  3. Burdyńska, J.; Daniel, W.; Li, Y.; Robertson, B.; Sheiko, S.S.; Matyjaszewski, K. “Molecular Bottlebrushes with Bimodal Length Distribution of Side Chains” Macromolecules 48, 4813–4822 (2015).
  4. Cao, Z.; Carrillo, J.-M.; Sheiko, S.S.; Dobrynin, A.V. “Computer Simulations of Bottlebrushes: From Melts to Soft Networks” Macromolecules 48, 5006–5015 (2015).
  5. Zhou,J.; Li, Q,; Turner,S.A.; Ashby, V.S.; Sheiko, S.S. “Isothermal programming of triple shape memory”. Polymer 72, 464–470 (2015).
  6. Tippets, C.A.; Li, Q,; Fu, Y.; Donev, E.; Zhou,J.; Turner,S.A.; Jackson, A.S.; Ashby, V.S.; Sheiko, S.S.; Lopez, R. “Dynamic Optical Gratings Accessed by Reversible Shape Memory” ACS Applied Materials & Interfaces 7, 14288–14293 (2015).
  7. Kulikov, O.V.; Reuther, J.F.; McCandless, G.T.; Sun, H.J.; Li, Y.; Mahmood, S.M.; Sheiko, S.S.; Percec, V., and Novak, B.M. “Characterization of Fibrous Aggregated Morphologies and other Complex Architectures Self-assembled from Helical Alkyne and Triazole Polycarbodiimides (R)-and (S)-families in the Bulk and Thin Film”. Macromolecules 48, 4088–4103 (2015).
  8. Jackson, A.S.; Sheiko, S.S. Ashby, V.S. "Grafting Poly(OEGMA) Brushes from a Shape Memory Elastomer and Subsequent Wrinkling Behavior" Langmuir 31, 5489–5494 (2015).
  9. Burdyńska, J.; Li, Y.; Aggarwal, V.A.; Höger, S.; Sheiko, S.S.; Matyjaszewski, K. “Synthesis and Arm Dissociation in Molecular Stars with a Spoked Wheel Core and Bottlebrush Arms” J. Am. Chem. Soc. 136, 12762–12770 (2014).
  10. Li, Y.; Nese, A.; Hu, X.; Lebedeva, N.V.; LaJoie, T.W.; Burdyńska, J.; Stefan, M.C.; You, W.; Yang, W.; Matyjaszewski, K.; Sheiko, S.S. “Shifting Electronic Structure by Inherent Tension in Molecular Bottlebrushes with Polythiophene Backbones” ACS Macro Lett. 3, 738-742 (2014).
  11. Turner,S.A.; Zhou,J.; Sheiko, S.S.; Ashby, V.S. “Switchable Micropatterned Surface Topographies Mediated by Reversible Shape Memory.” ACS Applied Materials & Interfaces 6, 8017–8021 (2014).
  12. Zhou,J.; Turner,S.A.; Brosnan, S.A.; Li, Q,; Carrillo, J-M.Y.; Dobrynin, A.V.; Gang, O.; Ashby, V.S.; Sheiko, S.S. “Shapeshifting: Reversible Memory in Semicrystalline Elastomers” Macromolecules 47, 1768-1776 (2014).
  13. Wutzel, H.; Richter, F.; Li, Y.; Sheiko, S.S., Klok, H.-A. “Poly[N-(2-hydroxypropyl) Methacrylamide] Nanogels by RAFT Polymerization in Inverse Emulsion.” Polymer Chem. 5, 1711-1719 (2014)
  14. Elsen, A.M.; Li, Y.; Li, Q.; Sheiko, S.S.; Matyjaszewski, K . “Exploring Quality in Gradient Copolymers.” Macromol Rapid Comm 35, 133-140 (2014)
  15. Li, Y.; Nese, A.; Matyjaszewski, K.; Sheiko, S.S.; Molecular Tensile Machines: Anti-Arrhenius Cleavage of Disulfide Bonds.” Macromolecules 46, 7196-7201 (2013)
  16. Abbaspourrad, A.; Duncanson, W.J.; Lebedeva, N.V.; Kim, S.H.; Zhushma, A.; Datta, S.S.; Sheiko, S.S.; Rubinstein, M.; Weitz, D.A. “Microfluidic Fabrication of Stable Gas-Filled Microcapsules for Acoustic Contrast Enhancement” Langmuir 29, 12352–12357 (2013)
  17. Zhushma, A,; Lebedeva. N.V.; Sen, P.; Rubinstein, M.; Sheiko, S.S.; Dayton, P.A. “A system for acoustical and optical analysis of encapsulated microbubbles at ultrahigh hydrostatic pressures.” Rev. Sci. Instrum. 84, 055105/1-4 (2013).
  18. Stals, P.J.M; Li, Y.; Burdyńska, J.; Nicolaÿ, R.; Nese, A.; Palmans, A.R.A.; Meijer, E.W.; Matyjaszewski, K.; Sheiko. S.S. “How far can we push polymer architectures?” J. Am. Chem. Soc. 135, 11421-11424 (2013).
  19. Sheiko, S.S.; Zhou, J.; Arnold, J.; Neugebauer, D.; Matyjaszewski, K.; Tsitsilianis, C.; Tsukruk, V.V.; Carrillo, J-M.Y.; Dobrynin, A.V.; Rubinstein, M. “Perfect mixing of immiscible macromolecules at fluid interfaces.” Nature Materials 12, 735-740 (2013)
  20. Hosono, N.; Gillissen, M.; Li, Y.; Sheiko, S.S.; Palmans, A.; Meijer, E.W. “Orthogonal Self-Assembly in Folding Block Copolymers.” J. Am. Chem. Soc. 135, 501-510 (2013).
  21. Mukumoto, K.; Li, Y.; Nese, A.; Sheiko, S.S.; Matyjaszewski, K. "Synthesis and Characterization of Molecular Bottlebrushes Prepared by Iron Based ATRP" Macromolecules, 45, 9243-9249 (2012).
  22. Chen, K.; Merkel, T.J.; Pandya, A.; Napier, M.E.; Luft, J.C.; Daniel. W.; Sheiko, S.S.; DeSimone J.M. “Low Modulus Biomimetic Microgel Particles with High Loading of Hemoglobin.”: Biomacromolecules 13, 2748-2759 (2012).
  23. Lebedeva, N.V.; Nese, A.; Sun, F.C.; Matyjaszewski K.; Sheiko, S.S. “Anti–Arrhenius Cleavage of Covalent Bonds in Bottlebrush Macromolecules on Substrate” PNAS 109, 9276-9280 (2012).
  24. Wang, JY, Wang, Y.P.; Sheiko, S.S.; Betts, D.E.; DeSimone, J.M. “Tuning Multiphase Amphiphilic Rods to Direct Self-Assembly.” J. Am. Chem. Soc. 134, 5801-5806 (2012).
  25. Nese, A.; Li, Y.; Sheiko, S.S.; Matyjaszewski, K. “Synthesis of Molecular Bottlebrushes by Atom Transfer Radical Polymerization with ppm Amounts of Cu Catalyst.” ACS Macromol. Lett. 1, 991–994 (2012).
  26. Nese, A.; Li, Y.; Averick, S.; Kwak, Y.; Konkolewicz, D.; Sheiko, S.S.; Matyjaszewski, K. “Synthesis of Amphiphilic Poly(N-vinylpyrrolidone)-b-poly(vinyl acetate) Molecular Bottlebrushes.” ACS Macromol. Lett. 1, 227–231 (2012).
  27. Nese, A.; Lebedeva, N.V.; Sherwood, G.; Averick, S.; Li, Y.; Gao, H.F.; Peteanu, L.; Sheiko, S.S.; Matyjaszewski, K. “pH-Responsive Fluorescent Molecular Bottlebrushes Prepared by Atom Transfer Radical Polymerization.” Macromolecules 44 , 5905-5910 (2011).
  28. Yu-Su, S.Y.; Sun, F.C.; Sheiko, S.S.; Konkolewicz, D.; Lee, H.I; Matyjaszewski, K. “Molecular Imaging and Analysis of Branching Topology in Polyacrylates by Atomic Force Microscopy.” Macromolecules 44 , 5928-5936 (2011).
  29. Li, Y.; Nese, A,; Lebedeva, N.V.; Davis, T.; Matyjaszewski, K.; Sheiko, S.S. “Molecular Tensile Machines: Intrinsic Acceleration of Disulfide Reduction by Dithiothreitol.” J. Am. Chem. Soc. 133, 17479–17484 (2011).
  30. Nese A.; Sheiko S.S.; Matyjaszewski K. “Effect of residual copper on stability of molecular brushes prepared by atom transfer radical polymerization.” Europ. Polym J. 47, 1198-1202 (2011).
  31. Sheiko, S.S.; Panyukov, S.; Rubinstein, M. “Bond Tension in Tethered Macromolecules“ Macromolecules 44, 4520-4529 (2011). Park, I., Nese, A.; Pietrasik, J.; Matyjaszewski, K.; Sheiko, S.S. “Focusing bond tension in bottle-brush macromolecules during spreading.” J. Mater. Chem. 21, 8448-8453 (2011).
  32. Tang HY, Li YC, Lahasky SH, Sheiko SS, Zhang DH “Core-Shell Molecular Bottlebrushes with Helical Polypeptide Backbone: Synthesis, Characterization, and Solution Conformations.” Macromolecules 44, 1491-1499 (2011).
  33. Carrillo, J.-M. Y.; Sheiko, S. S.; Dobrynin, A.V. “Molecular dynamics simulations of bottlebrush macromolecules in two dimensional polymeric melts under flow conditions.” Soft Matter 7 , 2805-2811 (2011).
  34. Barrett MJ, Sun FC, Nese A, Matyjaszewski, K,; Carrillo JMY, Dobrynin AV, Sheiko SS “Size Separation of Macromolecules during Spreading.” Langmuir 26, 15339-15344 (2010).
  35. Park, I.; Shirvaniants, D.; Nese, A.; Matyjaszewski, K.; Rubinstein, M.; Sheiko, S.S. “Spontaneous and specific activation of chemical bonds in macromolecular fluids.” J. Am. Chem. Soc. 132, 12487–12491 (2010).
  36. Nese, A.; Kwak, Y.; Nicolay, R.; Barrett, M.; Sheiko, S.S.; Matyjaszewski, K. “Synthesis of Poly(vinyl acetate) Molecular Brushes by a Combination of Atom Transfer Radical Polymerization (ATRP) and Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization” Macromolecules 43, 4016-4019 (2010).

2009 - 2000

  1. Yu-Su, S.; Sheiko, S.S.; Lee, H.-il; Jakubowski, W.; Nese, A,; Matyjaszewski, K.; Anokhin, D.; Ivanov, D.I. “Crystallization of Molecular Brushes with Diblock Copolymer Side Chains.” Macromolecules 42, 9008-9017 (2009).
  2. Panyukov, S.V., Sheiko, S.S.; Rubinstein, M. “Amplification of tension in branched macromolecules.” Phys. Rev . Lett. 102, 148301/1-4 (2009).
  3. Park, I.; Nese, A.; Matyjaszewski, K.; Sheiko, S.S. “Molecular Tensile Testing Machines: Selective Scission of A Single Disulfide Bond by Adsorption-Induced Tension.” Macromolecules 42, 1805-1807 (2009).
  4. Panyukov, S.V., Zhulina, E.B.; Sheiko, S.S.; Randall, G.; Brock, J.; Rubinstein, M. “Tension Amplification in Molecular Brushes in Solutions and at Substrates” J. Phys. Chem. 113, 3750–3768 (2009).
  5. Lee, H.-I.; Boyce, J.B.; Nese, A.; Matyjaszewski, K.; Sheiko, S.S. “pH-Induced Conformational Changes of Loosely-Grafted Molecular Brushes Containing Poly (acrylic acid) Side Chains.“ Polymer 49, 5490-5496 (2008) .
  6. Yu-Su, S. Y.; Thomas, D.R.; Alford, J. E.; LaRue, I.; Pitsikalis, M.; Hadjichristidis, N.; DeSimone, J.M.; Dobrynin, A.V.; Sheiko, S.S. “Molding Block Copolymer Micelles: A Framework for Molding of Discrete Objects on Surfaces” Langmuir 24, 12671-12679 (2008).
  7. Lee, H.-il; Matyjaszewski, K.; Yu-Su, S.; Sheiko, S.S. “Hetero-Grafted Block Brushes with PCL and PBA Side Chains” Macromolecules 41, 6073-6080 (2008).
  8. LaRue, I.; Adam, M.; Rubinstein, M.; Pitsikalis, M.; Hadjichristidis, N.; Hammouda, B.; Lin, M.Y.; Ivanov, D.A.; Gearba, R.I.; Anokhin, D.V. and Sheiko, S.S. “Effect of the Soluble Block Size on Spherical Diblock Polymer Micelles” Macromolecules 41, 6555-6563 (2008).
  9. Lebedeva, N.V., Sun, F.C.; Lee, H.-il, Matyjaszewski, K., and Sheiko, S.S. “Fatal Adsorption of Brush–Like Macromolecules: High Sensitivity of C–C Bond Cleavage Rates to Substrate Surface Energy” J. Am. Chem. Soc. 130, 4228-4229 (2008).
  10. Min K., Yu S., Lee H.I., Mueller L, Sheiko S.S., Matyjaszewski K. “High yield synthesis of molecular brushes via ATRP in miniemulsion” Macromolecules 40, 6557-6563 (2007).
  11. Sun, F.C.; Dobrynin, A.V.; Shirvanyants, D.; Lee H.-I., Matyjaszewski, K.; Rubinstein, G.; Rubinstein, M.; and Sheiko, S.S. “A Flory Theorem for Structurally Asymmetric Mixtures“ Phys. Rev. Lett. 99, 137801 (2007).
  12. Gallyamov, M.O.; Tartsch, Mela, P.; Potemkin, I.I.; Sheiko, S.S.; Börner, H.G.; Matyjaszewski, K.; Khokhlov, A.R.; Möller, M. “Vapour-induced Spreading Dynamics of Adsorbed Linear and Brush-like Macromolecules as Observed by Environmental-SFM: Polymer Chain Statistics and Scaling Exponents” Journal of Polymer Science B: Polymer Physics 45, 2368-2379 (2007)
  13. Xu, H.; Shirvaniants, D.; Rubinstein, M.; Shabratov, D.; Beers, K.; Matyjaszewski, K.; Sheiko, S.S. “Molecular Pressure Sensors” Advanced Materials 19, 2930-2934 (2007).
  14. Cherian, A.E.; Sun, F.C.; Sheiko, S.S.; Coates, G.W. “Formation of Nanoparticles by Intramolecular Cross-Linking: Following the Reaction Progress of Single Polymer Chains by Atomic Force Microscopy.“ J. Am. Chem. Soc. 129, 11350-11351 (2007).
  15. Maynor, B.W.; LaRue, I.; Rolland, J.P.; Spontak, R.J. Sheiko, S.S.; Samulski, R.J.; Samulski, E.T.; DeSimone, J.M. “Molecular Nanomimetics: Replication of Viruses, Micelles and other Naturally-Occurring Objects” Small 3, 845-849 (2007).
  16. Tang, H.-Z.; Garland, E.R.; Novak, B.M.; He, J.; Polavarapu, P.L.; Sun, F.C.; Sheiko, S.S. “Helical Polyguanidines Prepared by Helix-Sense-Selective Polymerizations of Achiral Carbodiimides Using Enantiopure Binaphthol-Based Titanium Catalysts.” Macromolecules 40, 3575-3580 (2007).
  17. Gallyamov, M.O.; Tartsch, Mela, P.; Börner, H.G.; Matyjaszewski, K.; Sheiko, S.S.; Khokhlov, A.R.; Möller, M. “A scanning force microscopy study on the mobility of single brush-like macromolecules on a silicon substrate induced by coadsorption of small molecules.” Phys. Chem. Chem. Phys. 9, 346-352 (2007).
  18. Kim, K.T.; Han, J.; Ryu, C.Y.; Sun, F.C.; Sheiko, S.S.; Winnik, M.A.; Manners, I. ”Synthesis, Characterization, and AFM Studies of Dendronized Polyferrocenylsilanes.” Macromolecules 39, 7922-7930 (2006)
  19. Lee, H.I.; Jakubowski, W.; Matyjaszewski, K.; Yu, S.; Sheiko, S.S. “Cylindrical core-shell brushes prepared by a combination of ROP and ATRP” Macromolecules 39, 4983-4989 (2006).
  20. Kreutzer, G.; Ternat, C.; Nguyen, T. Q.; Plummer, C.J.G.; Månson, J.-A.E.; Castelletto, V.; Hamley, I.W.; Sun, F.; Sheiko, S.S.; Klok, H-A. ”Water-Soluble, Unimolecular Containers Based On Amphiphilic Multiarm Star Block Copolymers” Macromolecules 39, 4507-4516 (2006).
  21. Sheiko, S.S.; Sun, F.; Randal, A.; Shirvaniants, D.; Matyjaszewski, K.; Rubinstein, M. “Adsorption-Induced Scission of Carbon-Carbon Bonds” Nature 440, 191-194 (2006).
  22. LaRue, I.; Adam, M.; Pitsikalis, M.; Hadjichristidis, N.; Rubinstein, M.; Sheiko, S.S. “Reversible Morphological Transitions of Polystyrene-b-Polyisoprene Micelles” Macromolecules 39, 309-314 (2006).
  23. Xu, H.; Sheiko, S.S.; Shirvaniants, D.; Rubinstein, M.; Beers, K.L.; Matyjaszewski, K.; “Flow induced epitaxial ordering of brush-like macromolecules on graphite” Langmuir 22, 1254-1259 (2006).
  24. Xu, H.; Shirvaniants, D.; Beers, K.L.; Matyjaszewski, K.; Dobrynin, A.V.; Rubinstein, M.; Sheiko, S.S. “Molecular visualization of conformation-triggered flow instability“ Phys. Rev. Lett. 94, 237801/1-4 (2005).
  25. Zhulina, E.B.; Adam, M.; LaRue, I.; Sheiko, S.S.; Rubinstein, M. “Diblock Copolymer Micelles in Dilute Solution” Macromolecules 38, 5330-5351 (2005).
  26. Lübbert, A.; Nguyen, T.Q.; Sun, F.; Sheiko, S.S.; Klok, H.-A. “l-Lysine Dendronized Polystyrene“ Macromolecules 38, 2064-2071 (2005).
  27. Logan, J.; Masse, P.; Dorvel, B.; Skolnik, A.; Sheiko, S.S.; Francis, R.; Taton, D.; Gnanou, Y.; Duran, R.S. "AFM study of micelle chaining in surface films of polystyrene-b-polyethylene oxide stars at the air/water interface" Langmuir 21, 3424-3431 (2005)
  28. Klok, H-A; Vandermeulen, G.W.M.; Nuhn, H.; Rösler, A.; Hamley, I.W.; Castelletto, V.; Xu,H.; Sheiko,S.S.”Peptide mediated formation of hierarchically organized solution and solid state polymer nanostructures” Faraday Discuss. 128, 29-41 (2005).
  29. Xu, H.; Shirvaniants, D.; Beers, K.; Matyjaszewski, K.; Rubinstein, M.; Sheiko, S.S. “Molecular Motion in a Spreading Precursor Film” Phys. Rev. Lett. 93, 206103/1-4, (2004).
  30. Sun, F.; Sheiko, S.S.; Möller, M.; Beers, K.; Matyjaszewski, K.; “Conformational switching of molecular brushes in response to the energy of interaction with the substrate“ Phys. Chem. A 108, 9682-9686 (2004).
  31. Gallyamov, M.O.; Tartsch, B.; Khokhlov, A.R.; Sheiko, S.S.; Börner, H.G.; Matyjaszewski, K.; Möller, M. “Real-Time Scanning Force Microscopy of Macromolecular Conformational Transitions“ Macromol. Rapid Comm. 25, 1703-1707 (2004).
  32. Gallyamov, M.O.; Tartsch, B.; Khokhlov, A.R.; Sheiko, S.S.; Börner, H.G.; Matyjaszewski, K.; Möller, M. “Reversible Collapse of Brushlike Macromolecules in Ethanol and Water Vapours as Revealed by Real-Time Scanning Force Microscopy“ Chemistry - A European Journal 10, 4599-4605 (2004).
  33. Gallyamov, M.O.; Tartsch, B.; Khokhlov, A.R.; Sheiko, S.S.; Börner, H.G.; Matyjaszewski, K.; Möller, M. “Conformational dynamics of single molecules visualized in real time by scanning force microscopy: macromolecular mobility on a substrate surface in different vapours” J. Microscopy 215, 245-256 (2004).
  34. Boyce, J.R.; Shirvanyants, D.; Sheiko, S.S.; Ivanov, D.A.; Qin, S.H.; Börner, H.G.; Matyjaszewski, K. “Multiarm cylindrical brushes: effect of the number of arms on the molecular weight polydispersity and surface ordering” Langmuir 20, 6005-6011 (2004).
  35. Neugebauer, D.; Sumerlin, B.; Matyjaszewski, K Goodhart, B.; Sheiko, S.S.; “How Dense are Cylindrical Brushes Grafted from a Multifunctional Macroinitiator?” Polymer 45, 8173-8179 (2004).
  36. Li, J.; Gauthier, M.; Teertstra, S.J.; Hu, X.; Sheiko, S.S. “Synthesis of Arborescent Polystyrene-graft-polyisoprene Copolymers using Acetylated Substrates“ Macromolecules 37, 795-802 (2004).
  37. Potemkin, I.I.; Khokhlov, A.R.; Sheiko, S.S.; Prokhorova, S.A.; Beers, K.; Matyjaszewski, K. “Spontaneous Curvature of Comb-Like Polymers at a Flat Interface” Macromolecules 37, 3918-3923 (2004).
  38. Lord, S.J., Sheiko, S.S.; LaRue, I.; Qin, S.; Lee, H-I.; Matyjaszewski, K. “Tadpole Conformation of Gradient Polymer Brushes” Macromolecules 37, 4235-4240, (2004).
  39. Vandermeulen, G.W.M.; Hinderberger,D.; Xu,H.; Sheiko,S.S.; Jeschke,G.; Klok, H-A ” Structure and dynamics of self-assembled poly(ethylene glycol) based coiled-coil Nano objects” Phys. Chem. Phys. 5, 488-494 (2004).
  40. Sheiko, S.S.; Borisov, O.V.; Prokhorova, S.A., Schmidt U, Möller, M.; Schmidt, M. “Microsegregation of Cylindrical Molecular Brushes: Microscopic Observation and Scaling Analysis” Europ. Phys. J. E 13, 125-131 (2004).
  41. LaRue, I.; Adam, M.; Sheiko, S.S.; Rubinstein, M. “Wormlike Micelles of Block Copolymers: Measuring the Linear Density by AFM and Light Scattering” Macromolecules 37, 5002-5005 (2004).
  42. Qin, S.; Matyjaszewski, K.; Xu, H.; Sheiko, S.S. “Synthesis and Visualization of Densely Grafted Molecular Brushes with Crystallizable Poly(octadecyl methacrylate) Block Segments” Macromolecules 36, 605-612 (2003).
  43. Sheiko, S.S.; daSilva, M.; Shirvaniants, D.G.; LaRue, I.; Prokhorova, S.A.; Beers, K.; Matyjaszewski, K. “Measuring Molecular Weight by Atomic Force Microscopy” J. Am. Chem. Soc. 125, 6725-6728 (2003).
  44. Matyjaszewski, K.; Qin, S.H.; Boyce, J.R.; Shirvanyants, D.; Sheiko, S.S. “Effect of initiation conditions on the uniformity of three-arm star molecular brushes“ Macromolecules 36, 1843-1849 (2003).
  45. Neugebauer, D.; Zhang, Y.; Pakula, T.; Sheiko, S.S.; Matyjaszewski, K. “Densely Grafted and Double-Grafted PEO Brushes via ATRP. A Route to Soft Elastomers” Macromolecules 36, 6746-6755 (2003).
  46. Börner, H.G.; Duran, D.; Matyjaszewski, K.; DaSilva, M.; Sheiko, S.S. “Synthesis of Molecular Brushes with Gradient in Grafting Density by Atom Transfer Polymerization” Macromolecules 35, 3387 -3394 (2002).
  47. Börner, H.G.; Beers, K.; Matyjaszewski, K.; Sheiko, S.S.; Möller, M. “Synthesis of Molecular Brushes with Block Copolymer Side Chains Using Atom Transfer Radical Polymerization” Macromolecules 34, 4375-4383 (2001).
  48. Sheiko, S.S.; Prokhorova, S.A.; Beers, K.; Matyjaszewski, K.; Potemkin, I.I.; Khokhlov, A.R.; Möller, M. “Single Molecule Rod-Globule Phase Transition for Brush Molecules at a Flat Interface” Macromolecules 34, 8354-8360 (2001).
  49. Sheiko, S.S.; Slangen, P-J.; Krupers, M.; Mourran, A.; Möller, M "Wetting Behavior of Thin Films of Polymethacrylates With Oligo(hexafluoropropene oxide) Side Chains“ in “Fluorinated Surfaces, Coatings, and Films” D.G. Castner, D.W. Graigner, Eds. ACS Symposium Series 787, 71-82 (2001).
  50. Khalatur, P.G., Khokhlov, A.R.; Prokhorova, S.A., Sheiko, S.S.; Möller, M.; Reineker, P. Shirvanyanz, D.G.; Starovoitova, N. “Unusual Conformation of Cylindrical Brushes Strongly Adsorbed on a Flat Solid Substrate” Europ. Phys. J. E 1, 99-103 (2000).
  51. Zhang, X.-Y.; Klein, J.; Sheiko, S.S.; Muzafarov, A. “Normal and Shear Behavior Between Two Mica Surfaces with Adsorbed Carbosiloxane Dendrimer” Langmuir 16, 3893-3901 (2000).
  52. Beginn, U.; Sheiko, S.S.; Möller. M “Self-Organisation of 3,4,5-Tris-(octyl-oxy)-benz-amide in Solution and Embedding of the Aggregates into Methacrylate Resins“ Macromol. Chem. Phys. 201 , 1008-1015 (2000).
  53. Prokhorova, S.A.; Sheiko, S.S.; Mourran, A.; Möller, M.; Beginn, U.; Zipp, G.; Ahn, C.-H.; Percec, V. "Epitaxial Crystallization of Monodendron Jacketed Linear Polymers on HOPG: studied by SFM and STM“ Langmuir 16, 6862 -6867 (2000).

1999 - 1989

  1. Sheiko, S.S.; Prokhorova S.A.; Schmidt U.; Dziezok, P.; Schmidt, M. ; Möller,M "Sparse Coatings by Disperse Adsorption of Molecular Brushes“ ACS Symposium Series 741 Tsukruk V.V.; Wahl, K.J. Eds. 346-355 (1999).
  2. Gerle, M.; Fischer, K.; Schmidt, M.; Roos, S.; Müller, A.H.E.; Sheiko, S.S.; Prokhorova, S.A.; Möller, M. "Main Chain Conformation and Anomalous Elution Behabior of Cylindrical Brushes by GPC/MALLS, Light Scattering and SFM“ Macromolecules 32, 2629-2637 (1999).
  3. Prokhorova, S.A.; Sheiko, S.S.; Ahn, C.-H.; Percec, V.; Möller, M. "Molecular Conformations of Monodendron Jacketed Polymers by Scanning Force Microscopy“ Macromolecules 32, 2653-2660 (1999).
  4. Schwegler, L.A.; Sheiko, S.S.; Möller, M.; Fossum, E.; Matyjaszewski, K. “Preparation of Telechelic Polysilylenes: A General Methology for the Synthesis of Polysilylene Based Triblock Copolymers” Macromolecules 32, 5901-5904 (1999).
  5. Emmerich, O.; Hugenberg, Schmidt, M.; N.; Sheiko, S.S.; Baumann, F.; Deubzer, B.; Weis, J.; Ebenhoch, J. “Molecular Boxes Based on Hollow Organosilicon Micronetworks” Advanced Materials 11, 1299-1303 (1999)
  6. Mazo, M.A.; Zhilin, P.A.; Gusarova, E.B. ; Sheiko, S.S.; Balabaev, N.K "Computer Simulation of Itramolecular Mobility of Dendrimers“ J. Molec. Liquids 82, 105-116 (1999).
  7. Mazo, M.A.; Zhilin, P.A.; Gusarova, E.B. ; Sheiko, S.S.; Balabaev, N.K "Molecular Dynamics Simulation of Dendrimer Itramolecular Mobility“ (Russian) Izvestiya Akadem. Nauk, Ser. Fiz. 62, 1098-1102 (1998).
  8. Percec, V.; Ahn, C.-H., Ungar, G.; Yeardley, D.J.P.; Möller, M.; Sheiko, S.S. "Spherical and Cylindrical Supermolecules from Polymer Backbones Jacketed with Quasi-Equivalent Dendritic Coats" Nature 391, 161-164 (1998).
  9. Krupers, M.J.; Sheiko, S.S.; Möller, M. "Micellar morphology of a Semifluorinated Diblock Copolymer“ Polym. Bull. 40, 211-217 (1998).
  10. Prokhorova, S.A.; Sheiko, S.S.; Möller, M., Ahn, C.-H.; Percec, V. "Molecular Imaging of Monodendron Jacketed Linear Polymers by Scanning Force Microscopy“ Makromol. Rapid Comm. 19, 359-366 (1998).
  11. Spatz, J.P.; Sheiko, S.S.; Möller, M. "Shape and Quality Control of Modified Scanning Force Microscopy Tips" Ultramicroscopy 75, 1-4 (1998).
  12. Hempenius, M.A.; Langeveld-Voss, B.M.W.; van Haare, J.A.E.H.; Janssen, R.A.J.; Sheiko, S.S.; Spatz, J.P.; Möller, M.; Meijer, E.W. "A Polystyrene-Oligothiophene-Polystyrene Triblock Copolymer" J. Am. Chem. Soc. 120, 2798-2804 (1998).
  13. Percec, V.; Ahn, C.-H.; Cho, W.-D.; Jamieson, A.M.; Kim, J.; Leman, T.; Schmidt, M.; Gerle, M.; . Möller, M.; Prokhorova, S.A.; Sheiko, S.S.; Cheng, S.Z.D.; Zhang, A.; Ungar, G.; Yeardley, D.J.P. “Visualizable cylindrical macromolecules with controlled stiffness from backbones containing libraries of self-assembling dendritic side groups” J. Am. Chem.Soc. 120, 8619-8631 (1998).
  14. Polyakov, D.K.; Ignat'eva, G.M.; Rebrov, E.A.; Vasilenko, N.G.; Muzafarov, A.M.; Sheiko, S.S.; Möller, M. "Starl-shaped Multi-arm Poly(styrene-block-isoprene)" Polymer Science. Ser. A, 40, 876-883 (1998) Translated from Vysokomolekul. Soed. A40, 1421-1429 (1998).
  15. Huck, W.T.S.; van Veggel, F.C.J.M.; Sheiko, S.S.; Möller, M.; Reinhoudt, D.N. "Molecularly Thin Films of Metallodendrimers" J. Phys. Org. Chem. 11, 540-545 (1998).
  16. Beers, K.; Gaynor, S.G;. Matyjaszewski, K., Sheiko, S.S.; Möller, M. “The synthesis of Densely Grafted Copolymers by Atom Transfer Radical Polymerization” Macromolecules 31, 9413-9415 (1998).
  17. Sheiko, S.S.; Buzin A.I.; Muzafarov, A.M.; Rebrov, E.A.; Getmanova, E.V. "Spreading of carbosilane dendrimers on the air/water interface“ Langmuir 14, 7468-7474 (1998). Sheiko S., Kunz M., Deckmann H., Möller M., "Nanofibrillar Structure of Gel-Drawn UHMW PE", Acta Polymerica 47, 492-497 (1997)
  18. Fossum, E.; Matyashevskij, K.; Sheiko, S.; Möller, M. "Morphology Studies of Polystyrene-block-Poly(methylphenylsilylene)" Macromolecules 30, 1765-1767 (1997). Sheiko, S.S.; Gauthier, M.; Möller, M. "Film Formation of Arborescent Graft Polystyrenes" Macromolecules 30, 2343-2349 (1997).
  19. Sheiko, S.S.; Gerle, M.; Fischer, M.; Schmidt, M.; Möller, M. "Worm-like Polystyrene Brushes in Thin Films“ Langmuir 13, 5368-5772 (1997).
  20. Sheiko, S.S.; Muzafarov, A.M.; Winkler, R.G.; Getmanova, E.V.; Eckert, G.; Reineker, P. "Contact Angle Microscopy on a Carbosilane Dendrimer with Hydroxyl End Groups: A Method for Mesoscopic Characterization of the Surface Structure" Langmuir 13, 4172-4181 (1997).
  21. Spatz, J.P.; Sheiko, S.; Möller, M.; Winkler, R.; Reineker, P.; Marti, O. "Tapping Scanning Force Microscopy in Air - Theory and Experiment" Langmuir 13, 4699-4703 (1997).
  22. Mazo, M.A.; Sheiko, S.S.; Perov, N.S.; Gusarova, E.B.; Balabaev, N.K. "Molecular Dynamic Simulation of Molecular Structure of Carbosilane Dendrimers“ Izvestiya of Russian Academy of Sciences, Phys. Ser. 61, 1728 (1997).
  23. Baumann, F.; Deubzer, B.; Geck, M.; Dauth, J.; Sheiko, S.S.; Schmidt, M. "Soluble Organosilicon-Micronetworks with Spatially Confined Reaction Sites" Advanced Materials 9, 955-958 (1997)
  24. Dziezok, P.; Sheiko, S.S.; Fischer, K.; Schmidt, M.; Möller, M. "Cylindrical Molecular Brushes" Angew. Chemie 109, 2894-2897 (1997). Int. Engl. Ed. 109, 2812-2815 (1997).
  25. Sheiko, S.S.; Frey, H.; Blomers, B.; Möller, M. "Substrate-Induced Orientation of Poly(di-n-alkylsilylenes)" Langmuir 12, 584-587 (1996).
  26. Molenberg, A.; Sheiko, S.S.; Möller, M. "A Block Copolymer from Polystyrene and Columnar Liquid-Crystalline Polydiethylsiloxane" Macromolecules 29, 3397-3400 (1996).
  27. Sheiko, S.S.; Eckert, G.; Ignat'eva, G.; Muzafarov, A.M.; Spickermann, J.; Räder, H.J.; Möller, M. "Solid-like States of a Dendrimer Liquid Displayed by Scanning Force Microscopy" Macromol. Chemie, Rapid Comm. 17, 283-297 (1996).
  28. Spatz, J.P.; Sheiko, S.; Möller, M. "Ion Stabilized Block Copolymer Micelles - Film Formation and Inter Micellar Interaction" Macromolecules 29, 3220-3226 (1996).
  29. Spatz, J.P.; Sheiko, S.; Möller, M. "Substrate Induced Lateral Micro-Phase Separation by Self-ordering of a Diblock Copolymer" Advanced Materials , 8, 513-517 (1996)
  30. Sheiko, S.; Lermann, E.; Möller, M. "Self-Dewetting of Perfluoroalkylmethacrylate Films on Glass" Langmuir 12, 4015-4024 (1996)
  31. Winkler, R.G.; Spatz, J.P.; Sheiko, S.; Möller, M.; Reineker, P.; Marti, O. "Imaging Material Properties by Resonant Tapping Force Microscopy: A Model Investigation“ Phys. Rev. B. 54, 8908-8912 (1996)
  32. Spatz, J.P., Roescher, A.; Sheiko, S.S.; Krausch, G.; Möller, M. "Noble Metal Loaded Block Ionomers: Micelle Organization, Adsorption of Free Chains and Formation of Free Films", Adv. Mater. 7, 731-735 (1995).
  33. Spatz, J.; Sheiko, S.S.; Möller, M.; Winkler, R.; Reineker, P.; Marti O. "Forces Affecting the Substrate in Resonant Tapping Force Microscopy" Nanotechnology 6, 40-44, (1995).
  34. van der Laan, G.P., de Haas M.P., Hummel A., Frey H., Sheiko S.S., Möller M., "Anisotropic Radiation Induced Conductivity in Oriented Poly(di-n-hexyl-silylene) in solid state and in the Mesophase" Macromolecules 27, 1897 (1994).
  35. Sheiko, S.S.; Möller, M.; Reuvekamp, E.M.C.M.; Zandbergen, H.W. "Evaluation of the probing profile of scanning-force-microscopy tips" Ultramicroscopy 53, 371-380 (1994).
  36. Frey, H.; Sheiko, S.S.; Möller, M.; Wittmann, J.C.; Lotz, B. "Highly Oriented Poly(di-n-alkylsilylene) films on Oriented PTFE Substrates" Adv. Mater. 5, 917-919 (1993).
  37. Möller, M.; Frey, H.; Sheiko S.S. "Blending, gel drawing and UV-crosslinking of ultra high molecular weight polyethylene and poly(di-n-pentylsilylene)" Coll. Polym. Sci. 271, 345-353 (1993).
  38. Dickland, H.G.; Sheiko, S.S.; v. der Does, L.; Möller, M.; Bantjes, A. "An Atomic Force Microscopy Study on the morphology of elastomer-coagent blends" Polymer 34, 1773-1775, (1993).
  39. Magonov, S.N.; Sheiko, S.S.; Deblieck, R.A.C.; Möller, M. "Atomic Force Microscopy of gel-drawn ultra high molecular weight polyethylene" Macromolecules 23, 1380-1386, (1993).
  40. Sheiko S.S., Möller M., Cantow H.-J., Magonov S.N., "Scanning Force Microscopy of Nanofibrillar Structure of Drawn Polyethylene Tapes 1. Different Modes and Tips", Polymer Bulletin, 31, 693-698, (1993).
  41. Sheiko, S.S.; Möller, M.; Reuvekamp, E.M.C.M.; Zandbergen, H.W. "Calibration and evaluation of scanning-force-microscopy probes" Phys. Rev. B 48, 5675-5678, (1993).
  42. Sheiko, S.S.; Kunz, M.; Möller, M. "An Atomic Force Microscopy Study of the Necking Process of Gel Drawn Ultra-High Molecular Weight Polyethylene" Polymer Science 35, 1609-1617 (1994). Official Engl. Translation of Vysokomolekul. Soed. 35, nr.11, 1903-1912 (1993).
  43. Wawkuschewski, A., Cantow, H.-J.; Magonov, S.N.; Sheiko, S.S.; Möller, M. "Scanning Force Microscopy of Nanofibrillar Structure of Drawn Polyethylene Tapes 2. Measurements under Water" Polymer Bulletin 31, 699-705 (1993).
  44. Sheiko, S.S.; Frey, H.; Möller, M. "FT-IR studies of the mechanical responce of the crystalline fraction in ultrastrong polyethylene tapes" Coll. Polym. Sci. 270, 440, (1992).
  45. Sheiko, S.S., Vainilovitch, I.S.; Magonov, S.N. "FTIR spectroscopy of polymer films under uniaxial stretching. 2. Amorphous and semicrystalline polyethyleneterephatalate" Polym. Bull. 25, 499, (1991).
  46. Magonov, S.N.; Vainilovitch, S.N.; Sheiko, S.S. "FTIR spectroscopy of polymer films under uniaxial stretching. 1. Atactic polystyrene" Polym. Bull. 25, 491, (1991).
  47. Sheiko, S.S.; Oleinik, E.F. "Strain recovery in single crystal mats of polyethylene", Vysokomol. Soedin. (Russ.) B32 145, (1990).
  48. Sheiko, S.S.; Salamatina, O.B.; Rudnev, S.N.; Oleinik, E.F. "Mechanism of plastic deformation of glassy polymers. Amorphous poly(ethyleneterephtalate)“ Vysokomol. Soedin. (Russ.) B32, 1844, (1990).
  49. Jashin, A.; Sheiko, S.S.; Zhuk, A.; Vainilovitch, I.S.; Magonov, S.N. "Tensile machine for stretching of polymer films" Prib. Tehn. Eksp. (Russ.) 4, 246, (1989).

Reviews

  1. Zhou, J.; Sheiko, S.S. "Reversible Shape-Shifting in Polymeric Materials" J. Polym. Sci., Part B: Polymer Physics. 54, 1365-1380 (2016). DOI: 10.1002/polb.24014
  2. Li, Y.; Sheiko, S.S. “Molecular Mechanochemistry: Engineering and Implications of Inherently Strained Architectures” Topics in Current Chemistry. Springer. 369, 1-36 (2015) DOI: 10.1007/128_2015_627
  3. Sheiko, S.S.; Magonov, S.N. “Scanning Probe Microscopy of Polymers” in Polymer Science: A Comprehensive Reference. Volume 2: Polymer Characterization. Eds. Krzysztof Matyjaszewski and Martin Möller, (2012), Pages 559-605, ISBN: 978-0-08-087862-1, Elsevier
  4. Yuan, J.; Müller, A.H.E.; Matyjaszewski, K.; Sheiko, S.S. “Molecular brushes” in Polymer Science: A Comprehensive Reference. Volume 6: Macromolecular Architectures and Soft Nano-objects, Eds. Krzysztof Matyjaszewski and Martin Möller, (2012), Pages 199-264, ISBN: 978-0-08-087862-1, Elsevier.
  5. Lee, H-i.; Pietrasik, J; Sheiko, S.S.; Matyjaszewski, K. "Stimuli-Responsive Molecular Brushes" Progress in Polym. Sci. 35, 24-44, (2010). DOI: 10.1016/j.progpolymsci.2009.11.002
  6. Sheiko, S.S.; Sumerlin, B.S.; Matyjaszewski, K. “Cylindrical molecular brushes: Synthesis, characterization, and properties.” Progress in Polymer Science 33, 759-785 (2008).
  7. Sheiko S.S.; Möller M "Atomic Force Microscopy of Polymers: Imaging, Probing, and Lithography " in “Macromolecular Engineering : Precise Synthesis, Materials Properties, Applications” by Krzysztof Matyjaszewski, Yves Gnanou, and Ludwik Leibler (Eds.) v. 3, 1515-1574 (2007), ISBN: 978-3-527-31446-1.
  8. Sheiko, S.S. “Proximal Probe Molecular Analysis” (Invited Review) in the McGraw-Hill 2006 Yearbook of Science and Technology ISSN 0076-2016 pp. 263-267 (2006).
  9. Sheiko, S.S.; Sun, F.; Boyce, J. “Shape Responsive Molecules" Chapter in "Responsive Polymer Materials: Designs and Applications" Blackwell Professional Publishing ISBN-10 0-8138-2109-6 pp. 1-26 (2006).
  10. Sheiko S.S.; Möller M "Visualization of Molecules – A First Step to Manipulation and Controlled Response" Chem. Rev. 101, 4099-4123 (2001).
  11. Sheiko S.S.; Möller M "Hyperbranched Macromolecules: Soft Particles with Adjustable Shape and Capability to Persistent Motion" in Topics in Polymer Chemistry. Dendrimers III. 212, 137-175 (2001) Ed. F. Vögtle, Springer-Verlag, Heidelberg,.
  12. Sheiko S.S. "Imaging of Polymers Using Scanning Force Microscopy: From Superstructures to Individual Molecules" Adv. Polymer Sci 151, 61-174 (1999).
  13. Sheiko, S.S.; Möller, M. "Scanning Force Microscopy on the Orientation of Gel-crystallized Ultra High Molecular Weight Polyethylene" in "Oriented Polymer Materials" Eds. S.Fakirov, Hüthing & Wepf, Heidelberg, pp. 210-237 (1996).
  14. Sheiko, S.S.; Turetzki, A.A.; Hopken, J.; Möller, M. “Molecular Organization of Polystyrene and Polymethylmethacrylate with Fluorocarbon Side Chains” in Macromolecular Engineering, Ed. M.K. Mishra, Plenum Press, New York pp.219-227, (1995).

Patents

  1. Sheiko S.S., Lebedeva, N.V., Zhushma, A., "Acoustic Imaging with Expandable Microcapsules" U.S. Pat. Appl. 15/551, 366, (2018).
  2. Sheiko S.S., Möller M., Reuvekamp E.M.C.M., Rogalla H., “Mesoscopic Calibration of AFM Tips”, NL-9202179, (1992).
  3. Sheiko S.S. “Unimolecular Tweezers” (USA). U.S. Pat. Appl. Publ. (2008), US 2008221224 A1 20080911; Application: US 2007-682427 20070306. Priority: AN 2008:1101138
  4. Sheiko, S.S.; Rubinstein, M.; Panyukov, S. “Molecular Tension Amplifiers” U.S. Patent Application Serial No. No. 61/087,340 (2008).

Chameleon-like Elastomers

Structural Coloration

Active camouflage is widely recognized as a soft-tissue feature, and yet the ability to integrate adaptive coloration and tissuelike mechanical properties into synthetic materials remains elusive. We provide a solution to this problem by uniting these functions in moldable elastomers through the self-assembly of linear-bottlebrush-linear triblock copolymers. Microphase separation of the architecturally distinct blocks results in physically cross-linked networks that display vibrant color, extreme softness, and intense strain stiffening on par with that of skin tissue. Each of these functional properties is regulated by the structure of one macromolecule, without the need for chemical cross-linking or additives. These materials remain stable under conditions characteristic of internal bodily environments and under ambient conditions, neither swelling in bodily fluids nor drying when exposed to air.


Our group is engaged in exploring soft matter science in areas such as polymers, elastomers, and gels for different applications including actuators, implants, shape memory, encapsulation, contrast agents, and drug delivery.

 

Contact Us

Department of Chemistry
University of North Carolina at Chapel Hill
Chapel Hill, NC 27599-3290
  919-843-5270
  sergei@email.unc.edu

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